Molecular Thermodynamics
by McQuarrie, Simon
ISBN: 9781891389054 | Copyright 1999
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Evolved from McQuarrie and Simon’s best-selling textbook, Physical Chemistry: A Molecular Approach, this text focuses in on the thermodynamics portion of the course. Although many of the chapters in Molecular Thermodynamics are similar to chapters in the larger physical chemistry text, new material has been added throughout along with three entirely new chapters on _x001C_The Energy Levels of Atoms and Molecules,_x001D_ _x001C_Thermodynamics of Electrochemical Cells,_x001D_ and _x001C_Nonequilibrium Thermodynamics._x001D_ The text also includes five short _x001C_MathChapters,_x001D_ each with a special set of problems that will help students review and summarize the mathematical tools required to master the material. Worked examples and chapter-ending problems with solutions are also included throughout the book.
Published under the University Science Books imprint
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Front Cover (pg. I) | |
Front Endsheets (pg. II) | |
Contents (pg. iv) | |
Preface (pg. x) | |
Acknowledgments (pg. xii) | |
Chapter 1: Energy Levels of Atoms and Molecules (pg. 1) | |
1-1 (pg. 2) | |
1-2 (pg. 6) | |
1-3 (pg. 7) | |
1-4 (pg. 9) | |
1-5 (pg. 13) | |
1-6 (pg. 14) | |
1-7 (pg. 16) | |
1-8 (pg. 18) | |
1-9 (pg. 22) | |
1-10 (pg. 25) | |
1-11 (pg. 27) | |
Math Chapter A - Numerical Methods (pg. 39) | |
Chapter 2: Properties of Gases (pg. 49) | |
2.1 (pg. 49) | |
2.2 (pg. 54) | |
2.3 (pg. 60) | |
2.4 (pg. 67) | |
2.5 (pg. 70) | |
2.6 (pg. 77) | |
2.7 (pg. 82) | |
Math Chapter B - Probability and Statistics (pg. 95) | |
Chapter 3: Boltzmann Factor and Partition Functions (pg. 105) | |
3-1 (pg. 106) | |
3-2 (pg. 108) | |
3-3 (pg. 110) | |
3-4 (pg. 114) | |
3-5 (pg. 116) | |
3-6 (pg. 119) | |
3-7 (pg. 120) | |
3-8 (pg. 125) | |
Math Chapter C - Series and Limits (pg. 135) | |
Chapter 4: Partition Functions and Ideal Gases (pg. 143) | |
4-1 (pg. 143) | |
4-2 (pg. 145) | |
4-3 (pg. 149) | |
4-4 (pg. 152) | |
4-5 (pg. 155) | |
4-6 (pg. 158) | |
4-7 (pg. 160) | |
4-8 (pg. 163) | |
4-9 (pg. 166) | |
Math Chapter D - Partial Differentiation (pg. 175) | |
Chapter 5: First Law of Thermodynamics (pg. 185) | |
5-1 (pg. 185) | |
5-2 (pg. 188) | |
5-3 (pg. 192) | |
5-4 (pg. 193) | |
5-5 (pg. 196) | |
5-6 (pg. 198) | |
5-7 (pg. 200) | |
5-8 (pg. 202) | |
5-9 (pg. 205) | |
5-10 (pg. 207) | |
5-11 (pg. 210) | |
5-12 (pg. 217) | |
Math Chapter E - Binomial Distribution and Stirling's Approximation (pg. 229) | |
Chapter 6: Entropy and the Second Law of Thermodynamics (pg. 237) | |
6-1 (pg. 237) | |
6-2 (pg. 239) | |
6-3 (pg. 241) | |
6-4 (pg. 245) | |
6-5 (pg. 249) | |
6-6 (pg. 253) | |
6-7 (pg. 258) | |
6-8 (pg. 260) | |
6-9 (pg. 263) | |
Chapter 7: Entropy and the Third Law of Thermodynamics (pg. 273) | |
7-1 (pg. 273) | |
7-2 (pg. 275) | |
7-3 (pg. 277) | |
7-4 (pg. 278) | |
7-5 (pg. 279) | |
7-6 (pg. 281) | |
7-7 (pg. 285) | |
7-8 (pg. 288) | |
7-9 (pg. 289) | |
Chapter 8: Helmholtz and Gibbs Energies (pg. 301) | |
8-1 (pg. 301) | |
8-2 (pg. 304) | |
8-3 (pg. 308) | |
8-4 (pg. 313) | |
8-5 (pg. 316) | |
8-6 (pg. 319) | |
8-7 (pg. 321) | |
8-8 (pg. 325) | |
Chapter 9: Phase Equilibria (pg. 349) | |
9-1 (pg. 350) | |
9-2 (pg. 357) | |
9-3 (pg. 359) | |
9-4 (pg. 365) | |
9-5 (pg. 369) | |
Chapter 10: Solutions I: Liquid-Liquid Solutions (pg. 387) | |
10-1 (pg. 387) | |
10-2 (pg. 390) | |
10-3 (pg. 393) | |
10-4 (pg. 394) | |
10-5 (pg. 401) | |
10-6 (pg. 405) | |
10-7 (pg. 410) | |
10-8 (pg. 413) | |
10-9 (pg. 419) | |
Chapter 11: Solutions II: Solid-Liquid Solutions (pg. 439) | |
11-1 (pg. 439) | |
11-2 (pg. 443) | |
11-3 (pg. 448) | |
11-4 (pg. 451) | |
11-5 (pg. 453) | |
11-6 (pg. 459) | |
11-7 (pg. 463) | |
Chapter 12: Chemical Equilibrium (pg. 477) | |
12-1 (pg. 477) | |
12-2 (pg. 481) | |
12-3 (pg. 484) | |
12-4 (pg. 486) | |
12-5 (pg. 488) | |
12-6 (pg. 490) | |
12-7 (pg. 491) | |
12-8 (pg. 495) | |
12-9 (pg. 499) | |
12-10 (pg. 506) | |
12-11 (pg. 508) | |
12-12 (pg. 512) | |
Chapter 13: Thermodynamics of Electrochemical Cells (pg. 529) | |
13-1 (pg. 529) | |
13-2 (pg. 531) | |
13-3 (pg. 533) | |
13-4 (pg. 536) | |
13-5 (pg. 538) | |
13-6 (pg. 542) | |
13-7 (pg. 547) | |
13-8 (pg. 551) | |
13-9 (pg. 553) | |
13-10 (pg. 556) | |
13-11 (pg. 559) | |
13-12 (pg. 565) | |
Chapter 14: Nonequilibrium Thermodynamics (pg. 581) | |
14-1 (pg. 582) | |
14-2 (pg. 585) | |
14-3 (pg. 588) | |
14-4 (pg. 591) | |
14-5 (pg. 593) | |
14-6 (pg. 597) | |
14-7 (pg. 602) | |
14-8 (pg. 605) | |
14-9 (pg. 610) | |
14-10 (pg. 617) | |
14-11 (pg. 622) | |
14-12 (pg. 625) | |
Answers to Numerical Problems (pg. 639) | |
Illustration Credits (pg. 648) | |
Index (pg. 649) | |
Back Endsheets (pg. 655) | |
Back Cover (pg. 657) |
Donald A. McQuarrie
As the author of landmark chemistry books and textbooks, Donald McQuarrie's name is synonymous with excellence in chemical education. From his classic text on Statistical Mechanics to his recent quantum-first tour de force on Physical Chemistry, McQuarrie's best selling textbooks are highly acclaimed by the chemistry community. McQuarrie received his PhD from the University of Oregon, and is Professor Emeritus from the Department of Chemistry at the University of California, Davis.John D. Simon
John D. Simon became the first George B. Geller Professor of Chemistry at Duke University in 1998. He is currently Chair Chemistry Department at Duke and a faculty member of the Biochemistry, and Ophthalmology Departments of the Duke Medical Center. John graduated from Williams College in 1979 with a B.A. in Chemistry and received his Ph.D. from Harvard University in 1983. After a postdoctoral fellowship with Professor Mostafa El-Sayed at UCLA, John joined the faculty of the Department of Chemistry at UCSD in 1985.
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