Chemical Bonds
An Introduction to Atomic and Molecular Structure
by Gray
ISBN: 9780935702354 | Copyright 1994
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This profusely illustrated book by a world-renowned chemist and award-winning chemistry teacher provides a complete introduction to atomic and molecular structure and bonding for science students. Parts of the book are revised and expanded versions of sections from Basic Principles of Chemistry by Gray and Haight, Jr.
Published under the University Science Books imprint
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Front Cover (pg. i) | |
Preface (pg. v) | |
Contents (pg. vi) | |
Chapter 1 Atomic Structure (pg. 1) | |
1-1 Rutherford's Experiments and a Model for Atomic Structure (pg. 2) | |
1-2 Atomic Number and Atomic Mass (pg. 4) | |
1-3 Nuclear Structure (pg. 4) | |
1-4 Bohr Theory of the Hydrogen Atom (pg. 5) | |
1-5 Absorption and Emission Spectra of Atomic Hydrogen (pg. 9) | |
1-6 Ionization Energy of Atomic Hydrogen (pg. 15) | |
1-7 General Bohr Theory for a One-Electron Atom (pg. 15) | |
The need for a better theory (pg. 16) | |
1-8 Matter Waves (pg. 17) | |
1-9 The Uncertainty Principle (pg. 18) | |
1-10 Atomic Orbitals (pg. 20) | |
1-11 The Wave Equation and Quantum Numbers for the Hydrogen Atom (pg. 21) | |
Quantum number specification of orbitals (pg. 24) | |
1-12 Many-electron Atoms (pg. 34) | |
Chapter 2 Electronic Properties of Atoms and Molecules (pg. 41) | |
2-1 Lewis Structures for Atoms (pg. 42) | |
2-2 Effective Atomic Radii in Molecules (pg. 43) | |
2-3 Ionization Energies and Orbital Configurations (pg. 44) | |
2-4 Electron Affinity (pg. 48) | |
2-5 Covalent Bonding (pg. 50) | |
Hydrogen molecule-ion (pg. 51) | |
2-6 Properties of H2 and H+2 in a Magnetic Field (pg. 52) | |
2-7 Lewis Structures for Diatomic Molecules (pg. 52) | |
2-8 Ionic Bonding (pg. 53) | |
2-9 Electronegativity (pg. 55) | |
2-10 A Covalent Bond with Ionic Character; The HCI Molecule (pg. 57) | |
2-11 Lewis Structures for Polyatomic Molecules (pg. 58) | |
Carbon tetrachloride molecule (pg. 58) | |
Ammonia molecule (pg. 59) | |
Magnesium chloride, an ionic molecule (pg. 59) | |
Ammonium chloride molecule (pg. 60) | |
2-12 Molecules with Double and Triple Bonds (pg. 60) | |
2-13 Bonding to Heavier Atoms (pg. 62) | |
2-14 Resonance (pg. 64) | |
Chapter 3 Diatomic Molecules (pg. 70) | |
3-1 Molecules with 1s Valence Atomic Orbitals (pg. 71) | |
Net bonding (pg. 74) | |
3-2 Molecules with s and p Valence Atomic Orbitals (pg. 77) | |
Sigma orbitals (pg. 77) | |
Pi orbitals (pg. 80) | |
s-p Sigma hybridization (pg. 81) | |
3-3 Homonuclear Diatomic Molecules (pg. 85) | |
Lithium (pg. 85) | |
Beryllium (pg. 85) | |
Boron (pg. 85) | |
Carbon (pg. 87) | |
Nitrogen (pg. 87) | |
Oxygen (pg. 88) | |
Fluorine (pg. 88) | |
Neon (pg. 88) | |
3 4 Homonuclear Diatomic Molecules with n > 2 Valence Orbitals (pg. 89) | |
Na2 , K 2 , Rb2 , and Cs2 (pg. 89) | |
Cl2 , Br 2, and 12 (pg. 89) | |
3-5 Hydrogen Fluoride Molecule (pg. 90) | |
Dipole moment of HF (pg. 94) | |
3-6 A General AB Heteronuclear Diatomic Molecule (pg. 95) | |
BN (eight valence electrons) (pg. 96) | |
BO, CN, and CO+ (nine valence electrons) (pg. 100) | |
NO+, CO, and CN- (ten valence electrons) (pg. 100) | |
NO (eleven valence electrons) (pg. 100) | |
Chapter 4 Polyatomic Molecules (pg. 103) | |
4-1 Beryllium Hydride, BeH2 (pg. 104) | |
4-2 Localized Molecular Orbitals for BeH2 , BH3 , and CH4 (pg. 108) | |
4 3 Hydrogen in Bridge Bonds (pg. 114) | |
4 -4 Localized Molecular Orbital Theory for Molecules with Lone Electron Pairs-NH3 and H20 (pg. 116) | |
4 5 The Valence-Shell Electron-Pair Repulsion (VSEPR) Method and Molecular Geometry (pg. 121) | |
4-6 Polar and Nonpolar Polyatomic Molecules (pg. 124) | |
4-7 Single and Multiple Bonds in Carbon Compounds (pg. 126) | |
Ethylene (pg. 126) | |
Acetylene (pg. 129) | |
Benzene (pg. 130) | |
4-8 Molecular Spectroscopy (pg. 135) | |
Chapter 5 Transition-Metal Complexes (pg. 147) | |
5-1 d Orbitals in Bonding (pg. 150) | |
5-2 Ligand Field Theory for Octahedral Complexes (pg. 152) | |
d-d Transitions and light absorption (pg. 157) | |
Heats of hydration of hexaaquo complexes (pg. 158) | |
n Bonding in metal complexes (pg. 159) | |
Factors that influence the value of D-o (pg. 162) | |
5-3 Ligand Field Theory for Square Planar Complexes (pg. 164) | |
5-4 Ligand Field Theory for Tetrahedral Complexes (pg. 167) | |
5-5 Charge-Transfer Absorption Bands (pg. 169) | |
5-6 Effect of the Nature of the Metal and the Ligand on the Stabilities of Complexes (pg. 170) | |
Chelation and stability (pg. 171) | |
5-7 Organometallic n Complexes of Transition Metals (pg. 173) | |
5-8 Transition-Metal Complexes and Living Systems (pg. 176) | |
Chapter 6 Bonding in Solids (pg. 188) | |
6- I Types of Solids (pg. 189) | |
6-2 Molecular Solids (pg. 194) | |
Van der Waals forces (pg. 194) | |
P4 and SH (pg. 201) | |
Polar molecules and hydrogen bonds (pg. 202) | |
Polar molecules as solvents (pg. 206) | |
6-3 Metals (pg. 209) | |
Electronic bands in metals (pg. 210) | |
6-4 Nonmetallic Network Solids (pg. 213) | |
Semiconductors (pg. 216) | |
Silicates (pg. 218) | |
Appendix Physical Constants and Conversion Factors Used in Text (pg. 225) | |
Index (pg. 227) | |
Back Cover (pg. 233) |
Harry B. Gray
Harry Barkus Gray is the Arnold O. Beckman Professor of Chemistry and the Founding Director of the Beckman Institute at the California Institute of Technology. His main research interests center on inorganic spectroscopy, photochemistry, and bioinorganic chemistry, with emphasis on understanding electron transfer in proteins. For his contributions to chemistry, which include over 700 papers and 17 books, he has received the National Medal of Science from President Ronald Reagan (1986); the Linderstrøm-Lang Prize (1991); the Basolo Medal (1994); the Gibbs Medal (1994); the Chandler Medal (1999); the Harvey Prize (2000); the Nichols Medal (2003); the National Academy of Sciences Award in Chemical Sciences (2003); the Benjamin Franklin Medal in Chemistry (2004); the Wolf Prize in Chemistry (2004); the City of Florence Prize in Molecular Sciences (2006); six national awards from the American Chemical Society, including the Priestley Medal (1991); and 16 honorary doctorates. He is a member of the National Academy of Sciences; the American Academy of Arts and Sciences; the American Philosophical Society; an honorary member of the Italian Chemical Society; a foreign member of the Royal Danish Academy of Sciences and Letters; the Royal Swedish Academy of Sciences; and the Royal Society of Great Britain. He was California Scientist of the Year in 1988.
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